Issue 1, 2008
From the journal:

Chemical Communications

Spontaneous resolution of a 3D chiral polyoxometalate-based polythreaded framework consisting of an achiral ligand†

Ya-Qian Lan,a   Shun-Li Li,a   Zhong-Min Su,*a   Kui-Zhan Shao,a   Jian-Fang Ma,*a   Xin-Long Wanga  and  En-Bo Wang*a  

* Corresponding authors

a Institute of Functional Material Chemistry, Key Laboratory of Polyoxometalate Science of the Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun, China
E-mail: zmsu@nenu.edu.cn, jianfangma@yahoo.com.cn, wangenbo@public.cc.jl.cn
Tel: +86 431 85099108

Abstract

Two enantiomerically 3D chiral POM-based architectures have been constructed based on the achiral ligand bbi, [V10O26]4− polyoxoanion and mixed valence Cu(I/II) without a chiral auxiliary, and they represent the first examples of enantiomerically 3D POM-based compounds using achiral ligands.

Graphical abstract: Spontaneous resolution of a 3D chiral polyoxometalate-based polythreaded framework consisting of an achiral ligand

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Article information

DOI
https://doi.org/10.1039/B714413J
Article type
Communication
Submitted
18 Sep 2007
Accepted
06 Nov 2007
First published
14 Nov 2007

Chem. Commun., 2008, 58-60

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Spontaneous resolution of a 3D chiral polyoxometalate-based polythreaded framework consisting of an achiral ligand

Y. Lan, S. Li, Z. Su, K. Shao, J. Ma, X. Wang and E. Wang, Chem. Commun., 2008, 58 DOI: 10.1039/B714413J

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