Issue 5, 2008
From the journal:

Chemical Communications

Combination between lacunary polyoxometalates and high-nuclear transition metal clusters under hydrothermal conditions: first (3,6)-connected framework constructed from sandwich-type polyoxometalate building blocks containing a novel {Cu8} cluster†

Jun-Wei Zhao,a   Jie Zhang,a   Shou-Tian Zhenga  and  Guo-Yu Yang*a  

* Corresponding authors

a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter and Graduate School of the Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China
E-mail: ygy@fjirsm.ac.cn
Fax: (+86) 591-83710051

Abstract

An unprecedented (3,6)-connected 3-D framework constructed from sandwich-type polyoxometalate building blocks containing a {Cu8} cluster, [Cu(H2O)2]H2[Cu8(dap)4(H2O)2(α-B-GeW9O34)2] (dap = 1,2-diaminopropane) has been hydrothermally made, which provides a novel topological structure in transition metal substituted polyoxometalates.

Graphical abstract: Combination between lacunary polyoxometalates and high-nuclear transition metal clusters under hydrothermal conditions: first (3,6)-connected framework constructed from sandwich-type polyoxometalate building blocks containing a novel {Cu8} cluster

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Supplementary files

Article information

DOI
https://doi.org/10.1039/B713510F
Article type
Communication
Submitted
04 Sep 2007
Accepted
07 Nov 2007
First published
21 Nov 2007

Chem. Commun., 2008, 570-572

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Combination between lacunary polyoxometalates and high-nuclear transition metal clusters under hydrothermal conditions: first (3,6)-connected framework constructed from sandwich-type polyoxometalate building blocks containing a novel {Cu8} cluster

J. Zhao, J. Zhang, S. Zheng and G. Yang, Chem. Commun., 2008, 570 DOI: 10.1039/B713510F

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