Issue 2, 2008

Reactivity of a coordinatively unsaturated Cp*Ru(κ2-P,O) complex

Abstract

Whereas a new coordinatively unsaturated Cp*Ru(κ2-P,O) complex (1a) forms adducts with two-electron donors (including σ-H2 and µ-N2 ligands), double Si–H bond activation is observed upon treatment with Ph2SiH2 or PhSiH3, leading to the clean formation of products corresponding to the net insertion of a Ph2Si: or Ph(H)Si: fragment into the Ru–O bond of 1a.

Graphical abstract: Reactivity of a coordinatively unsaturated Cp*Ru(κ2-P,O) complex

Supplementary files

Article information

Article type
Communication
Submitted
31 Aug 2007
Accepted
18 Oct 2007
First published
25 Oct 2007

Chem. Commun., 2008, 250-252

Reactivity of a coordinatively unsaturated Cp*Ru(κ2-P,O) complex

M. A. Rankin, K. D. Hesp, G. Schatte, R. McDonald and M. Stradiotto, Chem. Commun., 2008, 250 DOI: 10.1039/B713386C

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