[Zn(H2O)4][Zn2Sn3Se9(MeNH2)]: a robust open framework chalcogenide with a large nonlinear optical response

Manolis J. Manos; Joon I. Jang; John B. Ketterson; Mercouri G. Kanatzidis

doi:10.1039/B712732D

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[Zn(H₂O)₄][Zn₂Sn₃Se₉(MeNH₂)]: a robust open framework chalcogenide with a large nonlinear optical response†

Manolis J. Manos,^a Joon I. Jang,^b John B. Ketterson^b and Mercouri G. Kanatzidis*^a

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* Corresponding authors

^a Department of Chemistry, 2145 Sheridan Road, Northwestern University, Evanston, USA
E-mail: m-kanatzidis@northwestern.edu
Fax: +1 847-491-593
Tel: +1 847-467-1541

^b Department of Physics and Astronomy, Northwestern University, Evanston, USA

Abstract

[Zn(H₂O)₄][Zn₂Sn₃Se₉(MeNH₂)] has an open polar framework based on supertetrahedral clusters with a unique double connectivity mode and exhibits a strong second harmonic generation response, excellent acid stability and proton exchange capacity.

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Article information

DOI: https://doi.org/10.1039/B712732D
Article type: Communication
Submitted: 17 Aug 2007
Accepted: 28 Nov 2007
First published: 18 Dec 2007

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Chem. Commun., 2008, 972-974

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[Zn(H₂O)₄][Zn₂Sn₃Se₉(MeNH₂)]: a robust open framework chalcogenide with a large nonlinear optical response

M. J. Manos, J. I. Jang, J. B. Ketterson and M. G. Kanatzidis, Chem. Commun., 2008, 972 DOI: 10.1039/B712732D

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