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Issue 5, 2008
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Pre-activation protocol leading to highly stereoselectivity-controllable glycosylations of oxazolidinone protected glucosamines

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Abstract

Under pre-activation glycosylation conditions, the 4,6-di-O-acetyl-N-acetyloxazolidinone protected donor afforded either excellent β- or α-stereoselectivity simply by means of the addition of hindered base TTBP or the absence of base, leading to the controllable stereochemistry of coupling reactions.

Graphical abstract: Pre-activation protocol leading to highly stereoselectivity-controllable glycosylations of oxazolidinone protected glucosamines

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Publication details

The article was received on 15 Aug 2007, accepted on 06 Nov 2007 and first published on 23 Nov 2007


Article type: Communication
DOI: 10.1039/B712591G
Citation: Chem. Commun., 2008,0, 597-599

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    Pre-activation protocol leading to highly stereoselectivity-controllable glycosylations of oxazolidinone protected glucosamines

    Y. Geng, L. Zhang and X. Ye, Chem. Commun., 2008, 0, 597
    DOI: 10.1039/B712591G

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