Issue 3, 2008
From the journal:

Chemical Communications

Self-assembled monolayer electrode of a diiron complex with a phenoxo-based dinucleating ligand: observation of molecular oxygenadsorption/desorption in aqueous media†‡

Tomohiko Inomata,*a   Kazuma Shinozaki,a   Yuya Hayashi,a   Hidekazu Arii,b   Yasuhiro Funahashi,a   Tomohiro Ozawaa  and  Hideki Masuda*a  

* Corresponding authors

a Department of Applied Chemistry, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya, Japan
E-mail: masuda.hideki@nitech.ac.jp
Fax: +81-52-735-5209
Tel: +81-52-735-5228

b Department of Chemistry, Gakushuin University, Mejiro, Toshima-ku, Tokyo, Japan

Abstract

The phenoxo-based dinucleating ligand, 2,6-bis[bis(6-pivalamido-2-pyridylmethyl)amino-methyl]-4-aminophenol (1), and its Fe2(II) complex, [Fe2(II)(1)(PhCOO)2](CF3SO3) (2), were prepared and 2 deposited on the Au surface (2/Au) is much more stable than in solution and exhibits redox behavior in aqueous media as well as reversible adsorption/desorption of oxygen at room temperature.

Graphical abstract: Self-assembled monolayer electrode of a diiron complex with a phenoxo-based dinucleating ligand: observation of molecular oxygen adsorption/desorption in aqueous media

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Article information

DOI
https://doi.org/10.1039/B711802C
Article type
Communication
Submitted
02 Aug 2007
Accepted
31 Oct 2007
First published
09 Nov 2007

Chem. Commun., 2008, 392-394

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Self-assembled monolayer electrode of a diiron complex with a phenoxo-based dinucleating ligand: observation of molecular oxygen adsorption/desorption in aqueous media

T. Inomata, K. Shinozaki, Y. Hayashi, H. Arii, Y. Funahashi, T. Ozawa and H. Masuda, Chem. Commun., 2008, 392 DOI: 10.1039/B711802C

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