Issue 24, 2007
From the journal:

Organic & Biomolecular Chemistry

Enantioselective Henry reaction catalyzed by a C2-symmetric bis(oxazoline)–Cu(OAc)2·H2O complex†

Sandeep K. Ginotraa  and  Vinod K. Singh*a  

* Corresponding authors

a Department of Chemistry, Indian Institute of Technology Kanpur, India
E-mail: vinodks@iitk.ac.in.
Fax: +91-512-2597436
Tel: +91-512-2597291

Abstract

A C2-symmetric diethyl iPr-bis(oxazoline)–Cu(OAc)2·H2O was found to be an efficient catalyst for catalyzing an enantioselective Henry reaction between nitromethane and various aldehydes to provide β-hydroxy nitroalkanes with high chemical yields (up to 95%) and enantiomeric excesses (up to 97%).

Graphical abstract: Enantioselective Henry reaction catalyzed by a C2-symmetric bis(oxazoline)–Cu(OAc)2·H2O complex

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B714153J
Article type
Paper
Submitted
13 Sep 2007
Accepted
12 Oct 2007
First published
29 Oct 2007

Org. Biomol. Chem., 2007,5, 3932-3937

Permissions

Request permissions

Enantioselective Henry reaction catalyzed by a C2-symmetric bis(oxazoline)–Cu(OAc)2·H2O complex

S. K. Ginotra and V. K. Singh, Org. Biomol. Chem., 2007, 5, 3932 DOI: 10.1039/B714153J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements