Issue 13, 2007
From the journal:

Organic & Biomolecular Chemistry

Cis double allylation of cyclopropenes using cyclopropylindium reagents

Tsunehisa Hirashita,*a   Fumio Shiraki,a   Kenji Onishi,a   Mamiko Oguraa  and  Shuki Arakia  

* Corresponding authors

a Omohi College, Graduate School of Engineering, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya, Japan
E-mail: hirasita@nitech.ac.jp
Fax: +81 52-735-5206
Tel: +81 52-735-5206

Abstract

The successive double allylation of cyclopropenes with allylindium sesquiiodide and allyl iodide proceeded with a cis-addition mode in the presence of other organometallics (e.g. Grignard reagent, cuprate, Et2Zn and Et3Al), giving the corresponding cis-diallylcyclopropanes in high yields.

Graphical abstract: Cis double allylation of cyclopropenes using cyclopropylindium reagents

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/B706539F
Article type
Paper
Submitted
30 Apr 2007
Accepted
18 May 2007
First published
05 Jun 2007

Org. Biomol. Chem., 2007,5, 2154-2158

Permissions

Request permissions

Cis double allylation of cyclopropenes using cyclopropylindium reagents

T. Hirashita, F. Shiraki, K. Onishi, M. Ogura and S. Araki, Org. Biomol. Chem., 2007, 5, 2154 DOI: 10.1039/B706539F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements