Issue 11, 2007
From the journal:

Organic & Biomolecular Chemistry

Microbial Baeyer–Villiger oxidation of terpenones by recombinant whole-cell biocatalysts—formation of enantiocomplementary regioisomeric lactones†

Petra Černuchováa  and  Marko D. Mihovilovic*a  

* Corresponding authors

a Institute of Applied Synthetic Chemistry, Vienna University of Technology, Getreidemarkt 9/163-OC, 1060 Vienna, Austria
E-mail: mmihovil@pop.tuwien.ac.at
Fax: +43-1-58801-15499
Tel: +43-1-58801-15420

Abstract

Recombinant whole-cell expression systems for Baeyer–Villiger monooxygenases of various bacterial origin were utilized in the regiodivergent biooxidation of cyclic terpenones enabling access to enantio- and regioisomeric lactones on preparative scale.

Graphical abstract: Microbial Baeyer–Villiger oxidation of terpenones by recombinant whole-cell biocatalysts—formation of enantiocomplementary regioisomeric lactones

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Article information

DOI
https://doi.org/10.1039/B703175K
Article type
Paper
Submitted
01 Mar 2007
Accepted
30 Mar 2007
First published
25 Apr 2007

Org. Biomol. Chem., 2007,5, 1715-1719

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Microbial Baeyer–Villiger oxidation of terpenones by recombinant whole-cell biocatalysts—formation of enantiocomplementary regioisomeric lactones

P. Černuchová and M. D. Mihovilovic, Org. Biomol. Chem., 2007, 5, 1715 DOI: 10.1039/B703175K

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