Issue 11, 2007
From the journal:

New Journal of Chemistry

The first 2D trinuclear Cd(ii)-complex with adenine nucleobase: hydrothermal synthesis, crystal structure and fluorescent properties†

En-Cui Yang,a   Hong-Kun Zhao,a   Bin Ding,a   Xiu-Guang Wanga  and  Xiao-Jun Zhao*a  

* Corresponding authors

a College of Chemistry & Life Science, Key Laboratory of Molecular Structure and Materials Performance, Tianjin Normal University, 300387, P. R. China
E-mail: xiaojun_zhao15@yahoo.com.cn
Fax: +86 2223766556
Tel: +86 2223766556

Abstract

The first 2D aggregate, {[Cd3(μ3-ade)2(ap)2(H2O)2]·1.5H2O}n (1) (where adeH = adenine; H2ap = adipic acid), with trinuclear Cd(II) as secondary building units, has been successfully synthesized, the compound shows scarce coordination modes (tridentate μ3-N3,N7,N9 for ade and hexadentate η1:η2:η2:η1 for flexible ap) and a novel crystal packing arrangement, exhibiting strong fluorescent emission properties.

Graphical abstract: The first 2D trinuclear Cd(ii)-complex with adenine nucleobase: hydrothermal synthesis, crystal structure and fluorescent properties

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Article information

DOI
https://doi.org/10.1039/B712387F
Article type
Letter
Submitted
13 Aug 2007
Accepted
13 Sep 2007
First published
21 Sep 2007

New J. Chem., 2007,31, 1887-1890

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The first 2D trinuclear Cd(II)-complex with adenine nucleobase: hydrothermal synthesis, crystal structure and fluorescent properties

E. Yang, H. Zhao, B. Ding, X. Wang and X. Zhao, New J. Chem., 2007, 31, 1887 DOI: 10.1039/B712387F

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