Issue 34, 2007
From the journal:

Journal of Materials Chemistry

Formation of Ni[C4(CN)8] from the reaction of Ni(COD)2 (COD = 1,5-cyclooctadiene) with TCNE in THF

Joel S. Miller*a  and  Konstantin I. Pokhodnyaa  

* Corresponding authors

a Department of Chemistry, University of Utah, Salt Lake City, UT, USA
E-mail: jsmiller@chem.utah.edu

Abstract

The dissolution of Ni(COD)2 (COD = 1,5-cyclooctadiene) into dichloromethane leads to decomposition and formation of a room temperature magnetic material, whereas the reaction of Ni(COD)2 and tetracyanoethylene (TCNE) in THF forms paramagnetic materials including NiII[C4(CN)8](THF)2·xTHF. These results are discussed in context with a recent report of a room temperature magnet based upon the reaction of Ni(COD)2 and TCNE in dichloromethane.

Graphical abstract: Formation of Ni[C4(CN)8] from the reaction of Ni(COD)2 (COD = 1,5-cyclooctadiene) with TCNE in THF

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Article information

DOI
https://doi.org/10.1039/B708675J
Article type
Communication
Submitted
07 Jun 2007
Accepted
25 Jul 2007
First published
02 Aug 2007

J. Mater. Chem., 2007,17, 3585-3587

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Formation of Ni[C4(CN)8] from the reaction of Ni(COD)2 (COD = 1,5-cyclooctadiene) with TCNE in THF

J. S. Miller and K. I. Pokhodnya, J. Mater. Chem., 2007, 17, 3585 DOI: 10.1039/B708675J

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