Issue 2, 2007
From the journal:

Green Chemistry

Highly efficient [2,3]-sigmatropic rearrangement of sulfur ylide derived from Rh(ii) carbene and sulfides in water

Mingyi Liaoa  and  Jianbo Wang*a  

* Corresponding authors

a Beijing National Laboratory of Molecular Sciences (BNLMS), Green Chemistry Center (GCC) and Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry Peking University, Beijing, China
E-mail: wangjb@pku.edu.cn
Fax: +8610-62751708
Tel: +8610-62757248

Abstract

The Doyle–Kirmse reaction, namely the [2,3]-sigmatropic rearrangement of sulfonium ylides generated from transition metal carbenoids and sulfides has been, for the first time, carried out in water.

Graphical abstract: Highly efficient [2,3]-sigmatropic rearrangement of sulfur ylide derived from Rh(ii) carbene and sulfides in water

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Article information

DOI
https://doi.org/10.1039/B612743F
Article type
Paper
Submitted
04 Sep 2006
Accepted
23 Nov 2006
First published
11 Dec 2006

Green Chem., 2007,9, 184-188

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Highly efficient [2,3]-sigmatropic rearrangement of sulfur ylide derived from Rh(II) carbene and sulfides in water

M. Liao and J. Wang, Green Chem., 2007, 9, 184 DOI: 10.1039/B612743F

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