Issue 47, 2007
From the journal:

Dalton Transactions

Access to well-defined isolated Fe(ii) centers on silica and their use in oxidation

Charbel Roukoss,a   Steven Fiddy,b   Aimery de Mallmann,a   Nuria Rendón,a   Jean-Marie Basset,a   Emile Kuntza  and  Christophe Copéret*a  

* Corresponding authors

a Laboratoire de Chimie Organometallique de Surface, CPE Lyon 43 Bd du 11 Novembre 1918, F-69616 Villeurbanne Cedex, France
E-mail: coperet@cpe.fr.

b Synchrotron Radiation Department, Beam-line 7.1, CCLRC Daresbury Laboratory, Warrington, UK

Abstract

Well-defined FeII isolated sites are obtained by reaction of diaryl-N,N′-diazadiene bis(neosilyl) iron (1) with an aerosil silica, SiO2-(700). This system can be used as a precursor for the catalytic oxidation of cyclohexene into cyclohexene oxide, cyclohexenol and cyclohexenone in the presence of H2O2.

Graphical abstract: Access to well-defined isolated Fe(ii) centers on silica and their use in oxidation

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Article information

DOI
https://doi.org/10.1039/B711015D
Article type
Paper
Submitted
18 Jul 2007
Accepted
08 Aug 2007
First published
03 Sep 2007

Dalton Trans., 2007, 5546-5548

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Access to well-defined isolated Fe(II) centers on silica and their use in oxidation

C. Roukoss, S. Fiddy, A. de Mallmann, N. Rendón, J. Basset, E. Kuntz and C. Copéret, Dalton Trans., 2007, 5546 DOI: 10.1039/B711015D

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