Issue 34, 2007
From the journal:

Dalton Transactions

Use of 1,10-phenanthroline in diiron dithiolate derivatives related to the [Fe–Fe] hydrogenase active site†

Pierre-Yves Orain,a   Jean-François Capon,a   Nelly Kervarec,b   Frédéric Gloaguen,a   François Pétillon,a   Roger Pichon,b   Philippe Schollhammer*a  and  Jean Talarmina  

* Corresponding authors

a UMR CNRS 6521, Chimie, Electrochimie Moléculaires et Chimique Analytique, UFR Sciences et Techniques Université de Bretagne Occidentale, CS 93837, Brest-cedex 3, France
E-mail: schollha@univ-brest.fr

b Service de RMN, UFR Sciences et Techniques, Université de Bretagne Occidentale, CS 93837, Brest-cedex 3, France

Abstract

Treatment of [Fe2(µ-pdt)(CO)6] (pdt = S(CH2)3S) with 1,10-phenanthroline (phen) in refluxing toluene affords the asymmetric complex [Fe2(µ-pdt)(CO)4(phen)] (1); the protonation of 1 with HBF4·OEt2 in CD2Cl2 at 203 K has been monitored by 1H NMR.

Graphical abstract: Use of 1,10-phenanthroline in diiron dithiolate derivatives related to the [Fe–Fe] hydrogenase active site

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Article information

DOI
https://doi.org/10.1039/B709287C
Article type
Communication
Submitted
19 Jun 2007
Accepted
09 Jul 2007
First published
16 Jul 2007

Dalton Trans., 2007, 3754-3756

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Use of 1,10-phenanthroline in diiron dithiolate derivatives related to the [Fe–Fe] hydrogenase active site

P. Orain, J. Capon, N. Kervarec, F. Gloaguen, F. Pétillon, R. Pichon, P. Schollhammer and J. Talarmin, Dalton Trans., 2007, 3754 DOI: 10.1039/B709287C

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