Kinetics and mechanism of the oxidation of water soluble porphyrin FeIIITPPS with hydrogen peroxide and the peroxomonosulfate ion†
Abstract
The overall six-electron O. Although no unambiguous proposal for the structure of Int2 can be made, it is most probably the product of the four-electron oxidation of the original FeIIITPPS, contains an iron-oxo center and has a dissociable