Issue 27, 2007
From the journal:

Dalton Transactions

New alkyl derivatives phosphine sulfonate (P–O) ligands. Catalytic activity in Pd-catalysed Suzuki–Miyaura reactions in water†‡

Eduardo J. García Suárez,a   Aurora Ruiz,a   Sergio Castillón,*b   Werner Oberhauser,c   Claudio Bianchinic  and  Carmen Claver*a  

* Corresponding authors

a Dept. de Química Inorgánica, Facultat de Química, Univesitat Rovira I Virgili, C/Marcel.li Domingo S/N, 43007 Tarragona, Spain
E-mail: carmen.claver@urv.cat
Fax: +34 977 559563
Tel: +34 977 559574

b Dept. de Química Orgánica, Facultat de Química, Univesitat Rovira I Virgili, C/Marcel.li Domingo S/N, 43007 Tarragona, Spain

c Istituto di Chimica dei Composti Organometallici (ICCOM-CNR), Area di Ricerca di Firenze, Via Madonna del Piano 10, 50019 Sesto Fiorentino, Italy

Abstract

Two novel bis(o-methoxyphenyl) phosphinoalkylsulfonate (P–O) ligands have been prepared through a new and sustainable synthetic route; they are air stable as well as water soluble and have been applied in Pd-catalysed Suzuki–Miyaura cross-coupling reactions in neat water in conjunction with microwave heating.

Graphical abstract: New alkyl derivatives phosphine sulfonate (P–O) ligands. Catalytic activity in Pd-catalysed Suzuki–Miyaura reactions in water

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Article information

DOI
https://doi.org/10.1039/B707590C
Article type
Communication
Submitted
18 May 2007
Accepted
21 May 2007
First published
08 Jun 2007

Dalton Trans., 2007, 2859-2861

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New alkyl derivatives phosphine sulfonate (P–O) ligands. Catalytic activity in Pd-catalysed Suzuki–Miyaura reactions in water

E. J. García Suárez, A. Ruiz, S. Castillón, W. Oberhauser, C. Bianchini and C. Claver, Dalton Trans., 2007, 2859 DOI: 10.1039/B707590C

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