Issue 12, 2007
From the journal:

Dalton Transactions

Complexation versusthiadiazole formation for reactions of thiosemicarbazides with copper(ii)

Elena López-Torres,a   Andrew R. Cowleya  and  Jonathan R. Dilworth*a  

* Corresponding authors

a Chemistry Research Laboratory, University of Oxford, 12 Mansfield Road, Oxford, UK
E-mail: jon.dilworth@chem.ox.ac.uk
Fax: +44 (0)1865-272690
Tel: +44 (0)1865-285151

Abstract

The reactions of N,N-substituted thiosemicarbazides with copper salts have been investigated and either copper(II) thiosemicarbazide complexes, 1,3,4-thiadiazolium salts or 1,3,5-thiadiazoles are obtained depending on the Cu(II) salt and solvent used.

Graphical abstract: Complexation versus thiadiazole formation for reactions of thiosemicarbazides with copper(ii)

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Article information

DOI
https://doi.org/10.1039/B617186A
Article type
Communication
Submitted
24 Nov 2006
Accepted
07 Feb 2007
First published
20 Feb 2007

Dalton Trans., 2007, 1194-1196

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Complexation versus thiadiazole formation for reactions of thiosemicarbazides with copper(II)

E. López-Torres, A. R. Cowley and J. R. Dilworth, Dalton Trans., 2007, 1194 DOI: 10.1039/B617186A

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