Issue 2, 2007
From the journal:

Dalton Transactions

Unexpected reduction pathway of a Co2+ salt to [HCo(CO)4] via [Co2(CO)8] in an ionic liquid†‡

Frédéric Hébrard,a   Philippe Kalck,*a   Lucien Saussine,b   Lionel Magnab  and  Hélène Olivier-Bourbigoub  

* Corresponding authors

a Laboratoire de Catalyse, Chimie Fine et Polymères, Ecole Nationale Supérieure des Ingénieurs en Arts Chimiques et Technologiques 118, route de Narbonne, Toulouse cedex 4, France
E-mail: Philippe.Kalck@ensiacet.fr

b Institut Français du Pétrole, BP 3, Vernaison, France

Abstract

In the 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)amide ionic liquid ([BMI][NTf2]), [Co(NTf2)2] is reduced under 5.5 MPa of H2–CO to [Co2(CO)8] prior to [HCo(CO)4], provided a pyridine ligand is present in the medium.

Graphical abstract: Unexpected reduction pathway of a Co2+ salt to [HCo(CO)4] via [Co2(CO)8] in an ionic liquid

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B616169N
Article type
Communication
Submitted
06 Nov 2006
Accepted
10 Nov 2006
First published
23 Nov 2006

Dalton Trans., 2007, 190-191

Permissions

Request permissions

Unexpected reduction pathway of a Co2+ salt to [HCo(CO)4] via [Co2(CO)8] in an ionic liquid

F. Hébrard, P. Kalck, L. Saussine, L. Magna and H. Olivier-Bourbigou, Dalton Trans., 2007, 190 DOI: 10.1039/B616169N

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements