Issue 3, 2007
From the journal:

Dalton Transactions

Grafting of cyclopentadienyl ruthenium complexes on aminosilane linker modified mesoporous SBA-15 silicates†

Ayyamperumal Sakthivel,a   Filipe M. Pedro,a   Anthony S. T. Chiangb  and  Fritz E. Kühn*ac  

* Corresponding authors

a Department für Chemie der Technischen Universität München, Lichtenbergstraße 4, Garching bei München, Germany

b National Central University, Chung-Li, Taiwan, Republic of China

c Department of Chemistry, Instituto Tecnológico e Nuclear (ITN), Estrada Nacional No 10, Sacavém, Portugal
E-mail: fekuhn@itn.pt
Fax: +351-219946185

Abstract

Cyclopentadienyl ruthenium phosphane and carbene complexes are grafted on the surface of mesoporous SBA-15 molecular sieves through an aminosilane linker. The nature of the support after the grafting is examined by powder XRD, TEM and N2 adsorption/desorption analysis. Elemental analysis, FT-IR, DRIFTS, TG-MS and MAS-NMR studies confirm the successful grafting of the complexes on the surface. The grafted materials are applied for catalytic aldehyde olefination and cyclopropanation.

Graphical abstract: Grafting of cyclopentadienyl ruthenium complexes on aminosilane linker modified mesoporous SBA-15 silicates

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B611550K
Article type
Paper
Submitted
10 Aug 2006
Accepted
24 Oct 2006
First published
15 Nov 2006

Dalton Trans., 2007, 320-326

Permissions

Request permissions

Grafting of cyclopentadienyl ruthenium complexes on aminosilane linker modified mesoporous SBA-15 silicates

A. Sakthivel, F. M. Pedro, A. S. T. Chiang and F. E. Kühn, Dalton Trans., 2007, 320 DOI: 10.1039/B611550K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements