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Issue 46, 2007
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New ligand platforms for developing the chemistry of the Ti[double bond, length as m-dash]N–NR2 functional group and the insertion of alkynes into the N–N bond of a Ti[double bond, length as m-dash]N–NPh2 ligand

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Abstract

Two broadly applicable strategies for extending the available ligand platforms of the virtually unexplored terminal Ti[double bond, length as m-dash]N–NR2 functional group are described, along with the highly selective room temperature insertion of alkynes into the N–N bond of Ti{MeN(CH2CH2NSiMe3)2}(NNPh2)(py) and the catalytic cis-diamination of PhC[triple bond, length as m-dash]CMe by diphenylhydrazine.

Graphical abstract: New ligand platforms for developing the chemistry of the Ti [[double bond, length as m-dash]] N–NR2 functional group and the insertion of alkynes into the N–N bond of a Ti [[double bond, length as m-dash]] N–NPh2 ligand

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Publication details

The article was received on 03 Aug 2007, accepted on 07 Sep 2007 and first published on 21 Sep 2007


Article type: Communication
DOI: 10.1039/B711941K
Citation: Chem. Commun., 2007,0, 4937-4939

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    New ligand platforms for developing the chemistry of the Ti[double bond, length as m-dash]N–NR2 functional group and the insertion of alkynes into the N–N bond of a Ti[double bond, length as m-dash]N–NPh2 ligand

    J. D. Selby, C. D. Manley, M. Feliz, A. D. Schwarz, E. Clot and P. Mountford, Chem. Commun., 2007, 0, 4937
    DOI: 10.1039/B711941K

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