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Issue 42, 2007
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Changes in electronic couplings of mixed-valence systems due to through-space intramolecular interactions

Teresa M. Figueira-Duarte,a  Vega Lloveras,b  José Vidal-Gancedo,b  Aline Gégout,a  Béatrice Delavaux-Nicot,a  Richard Welter,c  Jaume Veciana,*b  Concepció Rovira*b  and  Jean-François Nierengarten*a 
Author affiliations

* Corresponding authors

a Groupe de Chimie des Fullerènes et des Systèmes Conjugués, Laboratoire de Chimie de Coordination du CNRS (UPR 8241), 205 route de Narbonne, Toulouse Cedex 4, France
E-mail: jfnierengarten@lcc-toulouse.fr
Fax: +33 (0) 5 61 55 30 03

b Institut de Ciència de Materials de Barcelona, Campus Universitari de Bellaterra, Cerdanyola, Spain
E-mail: cun@icmab.es, vecianaj@icmab.es
Fax: +34 9 35 80 57 29

c Laboratoire DECOMET, Université Louis Pasteur 4, rue Blaise Pascal, Strasbourg, France
E-mail: welter@chimie.u-strasbg.fr
Fax: +33 (0) 3 90 24 12 29

Abstract

The strength of the electronic interactions between the two redox moieties in fullerene-substituted mixed-valence bis(ferrocenylethynyl)ethene derivatives is modulated by the through-space intramolecular electronic interactions of C60 with the bridging conjugated system.

Graphical abstract: Changes in electronic couplings of mixed-valence systems due to through-space intramolecular interactions

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Publication details

The article was received on 18 May 2007, accepted on 25 Jun 2007 and first published on 11 Jul 2007


Article type: Communication
DOI: 10.1039/B707522G
Citation: Chem. Commun., 2007,0, 4345-4347
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    Changes in electronic couplings of mixed-valence systems due to through-space intramolecular interactions

    T. M. Figueira-Duarte, V. Lloveras, J. Vidal-Gancedo, A. Gégout, B. Delavaux-Nicot, R. Welter, J. Veciana, C. Rovira and J. Nierengarten, Chem. Commun., 2007, 0, 4345
    DOI: 10.1039/B707522G

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