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Issue 27, 2007
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Tricarbonylmanganese(i)–lysozyme complex: a structurally characterized organometallic protein

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Abstract

The reaction of the new and structurally characterized covalent {Mn(CO)3(H2O)2}+–lysozyme adduct with NiS4 and NiN2S2 complexes generates binuclear Ni–Mn complexes; relevance to the reactivity of the protein-bound {Fe(CO)(CN)2} intermediate during maturation of [NiFe] hydrogenases is discussed.

Graphical abstract: Tricarbonylmanganese(i)–lysozyme complex: a structurally characterized organometallic protein

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Publication details

The article was received on 14 Mar 2007, accepted on 11 May 2007 and first published on 11 Jun 2007


Article type: Communication
DOI: 10.1039/B703887A
Chem. Commun., 2007, 2805-2807

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    Tricarbonylmanganese(I)–lysozyme complex: a structurally characterized organometallic protein

    M. Razavet, V. Artero, C. Cavazza, Y. Oudart, C. Lebrun, J. C. Fontecilla-Camps and M. Fontecave, Chem. Commun., 2007, 2805
    DOI: 10.1039/B703887A

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