Issue 46, 2007

Anion binding in (arene)ruthenium(ii)-based hosts

Abstract

Asymmetric ruthenium(II) complexes of a flexible aminomethylpyridine derivative exhibit diastereotopic ligand methylene protons, as measured by NMR spectroscopy; binding of external anions renders these protons equivalent possibly by increasing dynamically averaged symmetry; the amount of anion needed to raise average symmetry correlates to the anion binding constant.

Graphical abstract: Anion binding in (arene)ruthenium(ii)-based hosts

Supplementary files

Article information

Article type
Communication
Submitted
17 Aug 2007
Accepted
20 Sep 2007
First published
08 Oct 2007

Chem. Commun., 2007, 4955-4957

Anion binding in (arene)ruthenium(II)-based hosts

S. J. Dickson, S. C. G. Biagini and J. W. Steed, Chem. Commun., 2007, 4955 DOI: 10.1039/B712699A

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