Mark W. Davies, Adam J. Clarke, Guy J. Clarkson, Michael Shipman and James H. R. Tucker
Chem. Commun., 2007, 5078-5080
DOI:
10.1039/B712447C,
Communication
The molecular motion associated with atomic inversion at an aziridine nitrogen can be essentially halted by metal complexation; addition of a second chemical input that decomplexes the metal from the aziridine restores fast inversion (k = 40 s–1 at 303 K).
