Issue 47, 2007

Umbrella motion in aziridines: use of simple chemical inputs to reversibly control the rate of pyramidal inversion

Abstract

The molecular motion associated with atomic inversion at an aziridine nitrogen can be essentially halted by metal complexation; addition of a second chemical input that decomplexes the metal from the aziridine restores fast inversion (k = 40 sā€“1 at 303 K).

Graphical abstract: Umbrella motion in aziridines: use of simple chemical inputs to reversibly control the rate of pyramidal inversion

Supplementary files

Article information

Article type
Communication
Submitted
16 Aug 2007
Accepted
14 Sep 2007
First published
03 Oct 2007

Chem. Commun., 2007, 5078-5080

Umbrella motion in aziridines: use of simple chemical inputs to reversibly control the rate of pyramidal inversion

M. W. Davies, A. J. Clarke, G. J. Clarkson, M. Shipman and J. H. R. Tucker, Chem. Commun., 2007, 5078 DOI: 10.1039/B712447C

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