Issue 45, 2007
From the journal:

Chemical Communications

Rapid ligand substitution reactions in ionic liquids studied by stopped-flow technique†

Peter Illner,a   Simon Kern,a   Svetlana Begela  and  Rudi van Eldik*a  

* Corresponding authors

a Institute for Inorganic Chemistry, University of Erlangen-Nürnberg, Egerlandstr. 1, Erlangen, Germany
E-mail: Rudi.vanEldik@chemie.uni-erlangen.de
Fax: +49(0)9131 8527387
Tel: +49(0)9131 8527350

Abstract

Detailed kinetic studies on ligand substitution reactions of [MII(terpy)Cl]+ complexes (M = Pt, Pd; terpy = 2,2′:6′,2″-terpyridine) with thiourea as entering nucleophile were for the first time performed in the imidazolium based ionic liquid [emim][NTf2] using stopped-flow techniques, opening the route to study fast reactions of transition metal complexes in ionic liquids.

Graphical abstract: Rapid ligand substitution reactions in ionic liquids studied by stopped-flow technique

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Article information

DOI
https://doi.org/10.1039/B711563F
Article type
Communication
Submitted
30 Jul 2007
Accepted
15 Aug 2007
First published
11 Sep 2007

Chem. Commun., 2007, 4803-4805

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Rapid ligand substitution reactions in ionic liquids studied by stopped-flow technique

P. Illner, S. Kern, S. Begel and R. V. Eldik, Chem. Commun., 2007, 4803 DOI: 10.1039/B711563F

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