Issue 47, 2007

Bismesitylmagnesium: a thermally stable and non-nucleophilic carbon-centred base reagent for the efficient preparation of silyl enol ethers

Abstract

Bismesitylmagnesium has been established as an accessible, practical, convenient, and non-nucleophilic carbon-centred base reagent for efficient access to silyl enol ethers from a series of ketone substrates at readily utilisable temperatures.

Graphical abstract: Bismesitylmagnesium: a thermally stable and non-nucleophilic carbon-centred base reagent for the efficient preparation of silyl enol ethers

Supplementary files

Article information

Article type
Communication
Submitted
26 Jul 2007
Accepted
13 Sep 2007
First published
27 Sep 2007

Chem. Commun., 2007, 5049-5051

Bismesitylmagnesium: a thermally stable and non-nucleophilic carbon-centred base reagent for the efficient preparation of silyl enol ethers

W. J. Kerr, A. J. B. Watson and D. Hayes, Chem. Commun., 2007, 5049 DOI: 10.1039/B711407A

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