Issue 43, 2007
From the journal:

Chemical Communications

A novel approach for the direct conversion of alkylsulfonyl derivatives into alkylcarbonyl derivatives via tin-free radical carbonylation†‡

Sangmo Kim,a   Kyoung-Chan Lima  and  Sunggak Kim*a  

* Corresponding authors

a Center for Molecular Design & Synthesis and Department of Chemistry, School of Molecular Science, Korea Advanced Institute of Science and Technology, Daejeon, Korea
E-mail: skim@kaist.ac.kr
Fax: (+82) 42-869-8370

Abstract

A novel radical approach for the direct conversion of RSO2X into RCOX in a single step is devised; the present approach is very simple, highly efficient, and minimizes formation of by-product.

Graphical abstract: A novel approach for the direct conversion of alkylsulfonyl derivatives into alkylcarbonyl derivatives via tin-free radical carbonylation

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Article information

DOI
https://doi.org/10.1039/B710939C
Article type
Communication
Submitted
17 Jul 2007
Accepted
21 Aug 2007
First published
28 Aug 2007

Chem. Commun., 2007, 4507-4509

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A novel approach for the direct conversion of alkylsulfonyl derivatives into alkylcarbonyl derivatives via tin-free radical carbonylation

S. Kim, K. Lim and S. Kim, Chem. Commun., 2007, 4507 DOI: 10.1039/B710939C

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