Issue 42, 2007
From the journal:

Chemical Communications

Stereoselective synthesis of trisubstituted alkenylboranes by palladium-catalysed reaction of alkynyltriarylborates with aryl halides†

Naoki Ishida,a   Tomoya Miuraa  and  Masahiro Murakami*a  

* Corresponding authors

a Department of Synthetic Chemistry and Biological Chemistry, Kyoto University, Katsura, Kyoto, Japan
E-mail: murakami@sbchem.kyoto-u.ac.jp
Fax: +81 75 383 2748
Tel: +81 75 383 2747

Abstract

The palladium-catalysed reaction of alkynyltriarylborates with aryl halides afforded trisubstituted alkenylboranes, in which two different aryl groups were installed across the carbon–carbon double bond in a cis arrangement.

Graphical abstract: Stereoselective synthesis of trisubstituted alkenylboranes by palladium-catalysed reaction of alkynyltriarylborates with aryl halides

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Article information

DOI
https://doi.org/10.1039/B710472C
Article type
Communication
Submitted
10 Jul 2007
Accepted
03 Aug 2007
First published
15 Aug 2007

Chem. Commun., 2007, 4381-4383

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Stereoselective synthesis of trisubstituted alkenylboranes by palladium-catalysed reaction of alkynyltriarylborates with aryl halides

N. Ishida, T. Miura and M. Murakami, Chem. Commun., 2007, 4381 DOI: 10.1039/B710472C

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