Issue 33, 2007
From the journal:

Chemical Communications

Thorpe–Ingold effect on the conformation and photophysical properties of dialkylsilylene-spaced divinylarene copolymers†

Mei-Yu Yeh,a   Hsin-Chieh Lin,a   Shern-Long Lee,a   Chun-hsien Chen,‡a   Tsong-Shin Lim,b   Wunshain Fannb  and  Tien-Yau Luh*a  

* Corresponding authors

a Department of Chemistry National Taiwan University, Taipei, Taiwan 106
E-mail: tyluh@ntu.edu, chhchen@ntu.edu.tw
Fax: +886-2-2364-4971
Tel: +886-2-2363-6288

b Institute of Atomic and Molecular Sciences, Academia Sinica, Taipei, Taiwan 106

Abstract

Geminal disubstitution on silicon in dialkylsilylene-spaced divinylarene copolymers may dictate the conformation and photophysical properties of the copolymers, bulky iPr substituted copolymers being more folded than Me substituent analogues.

Graphical abstract: Thorpe–Ingold effect on the conformation and photophysical properties of dialkylsilylene-spaced divinylarene copolymers

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Article information

DOI
https://doi.org/10.1039/B709497N
Article type
Communication
Submitted
21 Jun 2007
Accepted
03 Jul 2007
First published
26 Jul 2007

Chem. Commun., 2007, 3459-3461

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Thorpe–Ingold effect on the conformation and photophysical properties of dialkylsilylene-spaced divinylarene copolymers

M. Yeh, H. Lin, S. Lee, C. Chen, T. Lim, W. Fann and T. Luh, Chem. Commun., 2007, 3459 DOI: 10.1039/B709497N

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