Issue 45, 2007
From the journal:

Chemical Communications

Chemo-, regio- and stereoselective preparation of silyl enol ethers from thiol esters and bis(iodozincio)alkane†

Akihiro Ooguri,a   Zenichi Ikedaa  and  Seijiro Matsubara*a  

* Corresponding authors

a Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyoutodaigaku-Katsura, Nishikyo, Kyoto, Japan
E-mail: matsubar@orgrxn.mbox.media.kyoto-u.ac.jp
Fax: (+81)75-3832461

Abstract

Treatment of thiol ester with bis(iodozincio)alkane in the presence of palladium catalyst followed by silylation affords Z-silyl enol ether chemo-, regio- and stereoselectively.

Graphical abstract: Chemo-, regio- and stereoselective preparation of silyl enol ethers from thiol esters and bis(iodozincio)alkane

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Article information

DOI
https://doi.org/10.1039/B709456F
Article type
Communication
Submitted
21 Jun 2007
Accepted
20 Aug 2007
First published
31 Aug 2007

Chem. Commun., 2007, 4761-4763

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Chemo-, regio- and stereoselective preparation of silyl enol ethers from thiol esters and bis(iodozincio)alkane

A. Ooguri, Z. Ikeda and S. Matsubara, Chem. Commun., 2007, 4761 DOI: 10.1039/B709456F

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