Issue 35, 2007
From the journal:

Chemical Communications

A small tris(imidazolium) cage forms an N-heterocyclic carbene complex with silver(i)†

Charlotte E. Willans,a   Kirsty M. Anderson,a   Peter C. Junk,b   Leonard J. Barbourc  and  Jonathan W. Steed*a  

* Corresponding authors

a Department of Chemistry, Durham University, South Road, Durham, UK
E-mail: jon.steed@durham.ac.uk
Fax: +44 (0)191 384 4737
Tel: +44 (0)191 334 2085

b School of Chemistry, Monash University, Clayton, Australia

c Department of Chemistry, University of Stellenbosch, Stellenbosch, South Africa

Abstract

A small, sterically rigid tris(imidazolium) cyclophane reacts with Ag2O to give an Ag(I) carbene complex in which one of the imidazolium moieties remains protonated.

Graphical abstract: A small tris(imidazolium) cage forms an N-heterocyclic carbene complex with silver(i)

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Article information

DOI
https://doi.org/10.1039/B708692J
Article type
Communication
Submitted
08 Jun 2007
Accepted
06 Jul 2007
First published
07 Aug 2007

Chem. Commun., 2007, 3634-3636

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A small tris(imidazolium) cage forms an N-heterocyclic carbene complex with silver(I)

C. E. Willans, K. M. Anderson, P. C. Junk, L. J. Barbour and J. W. Steed, Chem. Commun., 2007, 3634 DOI: 10.1039/B708692J

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