Issue 42, 2007
From the journal:

Chemical Communications

Oxidation of allylic alcohols to α,β-unsaturated carbonyl compounds with aqueous hydrogen peroxide under organic solvent-free conditions†

Yoshihiro Kon,a   Yoko Usuia  and  Kazuhiko Sato*a  

* Corresponding authors

a National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba Central 5 Higashi 1-1-1, Tsukuba, Ibaraki, Japan
E-mail: k.sato@aist.go.jp
Fax: +81 29 861 4852
Tel: +81 29 861 4852

Abstract

Allylic alcohols are chemoselectively oxidized to α,β-unsaturated carbonyl compounds in high yield with aqueous H2O2 in the presence of Pt black catalyst under organic solvent-free conditions. The catalyst is easily recyclable and effective for at least 7 cycles.

Graphical abstract: Oxidation of allylic alcohols to α,β-unsaturated carbonyl compounds with aqueous hydrogen peroxide under organic solvent-free conditions

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Article information

DOI
https://doi.org/10.1039/B708612A
Article type
Communication
Submitted
06 Jun 2007
Accepted
08 Aug 2007
First published
20 Aug 2007

Chem. Commun., 2007, 4399-4400

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Oxidation of allylic alcohols to α,β-unsaturated carbonyl compounds with aqueous hydrogen peroxide under organic solvent-free conditions

Y. Kon, Y. Usui and K. Sato, Chem. Commun., 2007, 4399 DOI: 10.1039/B708612A

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