Issue 43, 2007
From the journal:

Chemical Communications

An alkoxide-directed alkyne–allene cross-coupling for stereoselective synthesis of 1,4-dienes†

Heidi L. Shimpa  and  Glenn C. Micalizio*a  

* Corresponding authors

a Department of Chemistry, Yale University, New Haven, CT, USA
E-mail: glenn.micalizio@yale.edu
Fax: +1 (213) 423 6144

Abstract

A titanium alkoxide-mediated convergent coupling between internal alkynes and allenes is described for the regio- and stereocontrolled synthesis of substituted acyclic 1,4-dienes.

Graphical abstract: An alkoxide-directed alkyne–allene cross-coupling for stereoselective synthesis of 1,4-dienes

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Article information

DOI
https://doi.org/10.1039/B708256H
Article type
Communication
Submitted
31 May 2007
Accepted
09 Aug 2007
First published
23 Aug 2007

Chem. Commun., 2007, 4531-4533

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An alkoxide-directed alkyne–allene cross-coupling for stereoselective synthesis of 1,4-dienes

H. L. Shimp and G. C. Micalizio, Chem. Commun., 2007, 4531 DOI: 10.1039/B708256H

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