Issue 43, 2007
From the journal:

Chemical Communications

Stereocontrol mechanism in CO/p-methylstyrene copolymerisation catalysed by aryl-α-diimine Pd(ii) complexes†

Carla Carfagna,*a   Giuseppe Gatti,a   Luca Mosca,a   Alessandra Passeri,a   Paola Paolib  and  Annalisa Guerric  

* Corresponding authors

a Istituto di Scienze Chimiche “F. Bruner”, Università di Urbino, Piazza Rinascimento, Urbino, Italy
E-mail: schim@uniurb.it
Fax: (+39) 0722 303311
Tel: (+39) 0722 303312

b Dipartimento di Energetica “S. Stecco”, Università di Firenze, Via S. Marta, Firenze, Italy
E-mail: paolapaoli@unifi.it
Fax: (+39) 055 4796342
Tel: (+39) 055 4796340

c Centro Interdipartimentale di Cristallografia Strutturale, Università di Firenze, Via della Lastruccia, Sesto Fiorentino (FI), Italy

Abstract

Structural analysis of the first steps of isotactic CO/p-methylstyrene copolymerisation, catalysed by aryl-α-diimine Pd(II) complexes, highlights the influence of steric effects on the stereoselectivity of olefin insertion.

Graphical abstract: Stereocontrol mechanism in CO/p-methylstyrene copolymerisation catalysed by aryl-α-diimine Pd(ii) complexes

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Article information

DOI
https://doi.org/10.1039/B707107H
Article type
Communication
Submitted
16 May 2007
Accepted
13 Aug 2007
First published
21 Aug 2007

Chem. Commun., 2007, 4540-4542

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Stereocontrol mechanism in CO/p-methylstyrene copolymerisation catalysed by aryl-α-diimine Pd(II) complexes

C. Carfagna, G. Gatti, L. Mosca, A. Passeri, P. Paoli and A. Guerri, Chem. Commun., 2007, 4540 DOI: 10.1039/B707107H

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