Issue 40, 2007

Symmetry and optical spectra: a “silent” 1 : 2 Np(v)–oxydiacetate complex

Abstract

The 1 : 2 Np(V)–oxydiacetate complex, NpO2(ODA)23−, identified by single-crystal X-ray diffractometry for the first time, is centrosymmetric around the Np atom so that the f–f transitions of Np(V) are forbidden, resulting in the “silence” of the absorption and diffuse reflectance spectra of this complex in solution and the solid state in the near-IR and visible regions.

Graphical abstract: Symmetry and optical spectra: a “silent” 1 : 2 Np(v)–oxydiacetate complex

Supplementary files

Article information

Article type
Communication
Submitted
04 May 2007
Accepted
16 Jul 2007
First published
06 Aug 2007

Chem. Commun., 2007, 4119-4121

Symmetry and optical spectra: a “silent” 1 : 2 Np(V)–oxydiacetate complex

G. Tian, L. Rao and A. Oliver, Chem. Commun., 2007, 4119 DOI: 10.1039/B706825E

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