Issue 44, 2007
From the journal:

Chemical Communications

Synthesis of poly(para-phenylene)(2-isocyano-2-tosylpropane-1,3-diyl), poly(para-phenylene)(2-oxopropane-1,3-diyl) and oligo(cyclopentadienones) via carbonylative coupling of α,α′-dibromoxylene†

Robert G. Pottera  and  Thomas S. Hughes*a  

* Corresponding authors

a Department of Chemistry, Cook Physical Sciences Building, 82 University Place, University of Vermont, Burlington, VT 05401, USA
E-mail: Thomas.S.Hughes@uvm.edu
Fax: +1 802-656-8705
Tel: +1 802-656-0161

Abstract

Poly(para-phenylene)(2-oxopropane-1,3-diyl), a potential precursor of linear graphene, is generated in low yield from hydrolysis of a previously unknown poly(para-phenylene)(2-isocyano-2-tosylpropane-1,3-diyl) generated from inexpensive, commercially available starting materials.

Graphical abstract: Synthesis of poly(para-phenylene)(2-isocyano-2-tosylpropane-1,3-diyl), poly(para-phenylene)(2-oxopropane-1,3-diyl) and oligo(cyclopentadienones) via carbonylative coupling of α,α′-dibromoxylene

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Article information

DOI
https://doi.org/10.1039/B706807G
Article type
Communication
Submitted
08 May 2007
Accepted
03 Sep 2007
First published
24 Sep 2007

Chem. Commun., 2007, 4665-4667

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Synthesis of poly(para-phenylene)(2-isocyano-2-tosylpropane-1,3-diyl), poly(para-phenylene)(2-oxopropane-1,3-diyl) and oligo(cyclopentadienones) via carbonylative coupling of α,α′-dibromoxylene

R. G. Potter and T. S. Hughes, Chem. Commun., 2007, 4665 DOI: 10.1039/B706807G

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