Issue 30, 2007
From the journal:

Chemical Communications

Role of the isopropyl group in asymmetric autocatalytic zinc alkylations†

Jürgen Klankermayer,*a   Ilya D. Gridnev*b  and  John M. Brown*c  

* Corresponding authors

a Institut für Technische und Makromolekulare Chemie (ITMC), RWTH Aachen University, 52074 Aachen, Germany
E-mail: jKlankermayer@itmc.rwth-aachen.de
Fax: +49 (0)241 8022177

b Graduate School of Science and Engineering, Tokyo Institute of Technology, 2-12-1 I3-28 O-okayama, Meguro-ku, Tokyo 152-8552, Japan
E-mail: gridnev.i.aa@m.titech.ac.jp

c Chemical Research Laboratory, 12 Mansfield Rd, Oxford, UK
E-mail: john.brown@chem.ox.ac.uk
Fax: +44 (0)1865 285002

Abstract

The amplifying asymmetric autocatalysis discovered by Soai and co-workers is dependent on the unique steric properties of the isopropyl group.

Graphical abstract: Role of the isopropyl group in asymmetric autocatalytic zinc alkylations

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Article information

DOI
https://doi.org/10.1039/B705978G
Article type
Communication
Submitted
20 Apr 2007
Accepted
21 Jun 2007
First published
03 Jul 2007

Chem. Commun., 2007, 3151-3153

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Role of the isopropyl group in asymmetric autocatalytic zinc alkylations

J. Klankermayer, I. D. Gridnev and J. M. Brown, Chem. Commun., 2007, 3151 DOI: 10.1039/B705978G

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