Issue 36, 2007
From the journal:

Chemical Communications

A novel cyclization reaction between 2,3-bis(trimethylsilyl)buta-1,3-diene and acyl chlorides with straightforward formation of polysubstituted furans†

Francesco Babudri,ab   Stefania R. Cicco,b   Gianluca M. Farinola,a   Linda C. Lopez,a   Francesco Naso*ab  and  Vita Pintoa  

* Corresponding authors

a Dipartimento di Chimica, Università degli Studi di Bari, via Orabona, Bari, Italy

b CNR ICCOM Bari, Dipartimento di Chimica Università degli Studi di Bari, Bari, Italy
E-mail: f.naso@chimica.uniba.it

Abstract

A novel cyclization process of 2,3-bis(trimethylsilyl)buta-1,3-diene with various acyl chlorides in the presence of aluminium trichloride affords 2,5-disubstituted or 2,3,5-trisubstituted furans in short reaction time; a subsequent acylation process of the furan ring occurs if the reaction time is prolonged.

Graphical abstract: A novel cyclization reaction between 2,3-bis(trimethylsilyl)buta-1,3-diene and acyl chlorides with straightforward formation of polysubstituted furans

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Article information

DOI
https://doi.org/10.1039/B705257J
Article type
Communication
Submitted
10 Apr 2007
Accepted
28 Jun 2007
First published
09 Jul 2007

Chem. Commun., 2007, 3756-3758

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A novel cyclization reaction between 2,3-bis(trimethylsilyl)buta-1,3-diene and acyl chlorides with straightforward formation of polysubstituted furans

F. Babudri, S. R. Cicco, G. M. Farinola, L. C. Lopez, F. Naso and V. Pinto, Chem. Commun., 2007, 3756 DOI: 10.1039/B705257J

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