Issue 39, 2007
From the journal:

Chemical Communications

A discrete conglomerate of a distorted Mo(v)-porphyrin with a directly coordinated keggin-type polyoxometalate†

Atsutoshi Yokoyama,a   Takahiko Kojima,*a   Kei Ohkuboa  and  Shunichi Fukuzumi*a  

* Corresponding authors

a Osaka University and SORST (JST), 2-1 Yamada-oka, Suita, Osaka 565-0871, Japan
E-mail: kojima@chem.eng.osaka-u.ac.jp (T. K.), fukuzumi@chem.eng.osaka-u.ac.jp (S. F.)
Fax: +81-6-6879-7370

Abstract

The reaction of a saddle-distorted Mo(V)-dodecaphenylporphyrin complex and a Keggin-type polyoxometalate gives a discrete and nanosized molecule, [{Mo(DPP)(O)}2(H2SiW12O40)], which involves direct coordination between the Mo(V) centers and terminal oxo groups of the polyoxometalate and exhibits excellent stability in solution to show reversible multi-redox processes.

Graphical abstract: A discrete conglomerate of a distorted Mo(v)-porphyrin with a directly coordinated keggin-type polyoxometalate

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Article information

DOI
https://doi.org/10.1039/B704994C
Article type
Communication
Submitted
02 Apr 2007
Accepted
18 May 2007
First published
08 Jun 2007

Chem. Commun., 2007, 3997-3999

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A discrete conglomerate of a distorted Mo(V)-porphyrin with a directly coordinated keggin-type polyoxometalate

A. Yokoyama, T. Kojima, K. Ohkubo and S. Fukuzumi, Chem. Commun., 2007, 3997 DOI: 10.1039/B704994C

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