Issue 27, 2007
From the journal:

Chemical Communications

A new method for the generation of indole-2,3-quinodimethanes and 2-(N-alkoxycarbonylamino)-1,3-dienes. Intramolecular Heck/Diels–Alder cycloaddition cascade starting from acyclic α-phosphono enecarbamates†

Haruhiko Fuwa*a  and  Makoto Sasaki*a  

* Corresponding authors

a Laboratory of Biostructural Chemistry, Graduate School of Life Sciences, Tohoku University, 1-1 Tsutsumidori-amamiya, Aoba-ku, Sendai, Japan
E-mail: hfuwa@bios.tohoku.ac.jp, masasaki@bios.tohoku.ac.jp

Abstract

An intramolecular Heck/Diels–Alder cycloaddition cascade starting from acyclic α-phosphono enecarbamates has been developed to prepare nitrogen heterocycles viaindole-2,3-quinodimethanesand 2-(N-alkoxycarbonylamino)-1,3-dienes.

Graphical abstract: A new method for the generation of indole-2,3-quinodimethanes and 2-(N-alkoxycarbonylamino)-1,3-dienes. Intramolecular Heck/Diels–Alder cycloaddition cascade starting from acyclic α-phosphono enecarbamates

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Article information

DOI
https://doi.org/10.1039/B704374K
Article type
Communication
Submitted
22 Mar 2007
Accepted
17 Apr 2007
First published
01 May 2007

Chem. Commun., 2007, 2876-2878

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A new method for the generation of indole-2,3-quinodimethanes and 2-(N-alkoxycarbonylamino)-1,3-dienes. Intramolecular Heck/Diels–Alder cycloaddition cascade starting from acyclic α-phosphono enecarbamates

H. Fuwa and M. Sasaki, Chem. Commun., 2007, 2876 DOI: 10.1039/B704374K

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