A novel, facile route to β-fluoroamines by hydrofluorination using superacidHF–SbF5

Sébastien Thibaudeau; Agnès Martin-Mingot; Marie-Paule Jouannetaud; Omar Karam; Fabien Zunino

doi:10.1039/B703629A

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A novel, facile route to β-fluoroamines by hydrofluorination using superacidHF–SbF₅†

Sébastien Thibaudeau,*^a Agnès Martin-Mingot,^a Marie-Paule Jouannetaud,^a Omar Karam^b and Fabien Zunino^b

Author affiliations

* Corresponding authors

^a Université de Poitiers, CNRS UMR 6514, Laboratoire “Synthèse et Réactivité des Substances Naturelles”, 40, avenue du Recteur Pineau, France
E-mail: sebastien.thibaudeau@univ-poitiers.fr
Fax: +33-549453501
Tel: +33-549453702

^b @rtMolecule, 40, avenue du Recteur Pineau, France
E-mail: contact@artmolecule.fr
Fax: +33-549454121
Tel: +33-549454121

Abstract

A range of unsaturated amines and sulfonamides were converted to β-fluoro nitrogen analogues after hydrofluorination in superacidHF–SbF₅, based on the formation of highly reactive electrophilic intermediates.

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Supplementary files

Experimental procedures and NMR spectra PDF (8749K)

Article information

DOI: https://doi.org/10.1039/B703629A
Article type: Communication
Submitted: 29 Mar 2007
Accepted: 10 May 2007
First published: 07 Jun 2007

Download Citation

Chem. Commun., 2007, 3198-3200

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A novel, facile route to β-fluoroamines by hydrofluorination using superacidHF–SbF₅

S. Thibaudeau, A. Martin-Mingot, M. Jouannetaud, O. Karam and F. Zunino, Chem. Commun., 2007, 3198 DOI: 10.1039/B703629A

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