Issue 22, 2007
From the journal:

Chemical Communications

Anion templated surface assembly of a redox-active sensory rotaxane†

Simon R. Bayly,a   Thomas M. Gray,a   Michał J. Chmielewski,a   Jason J. Davis*a  and  Paul D. Beer*a  

* Corresponding authors

a Chemistry Research Laboratory, Department of Chemistry, University of Oxford, Mansfield Road, Oxford, UK
E-mail: jason.davis@chem.ox.ac.uk; paul.beer@chem.ox.ac.uk
Fax: 44 01865 272690
Tel: 44 01865 272600

Abstract

Anion templation is used to assemble novel redox-active bis-ferrocene functionalised rotaxane self-assembled monolayers (SAMs) on to gold electrode surfaces; after template removal, the unique SAM rotaxane binding domain is capable of selectively sensing chloride ions electrochemically.

Graphical abstract: Anion templated surface assembly of a redox-active sensory rotaxane

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Article information

DOI
https://doi.org/10.1039/B701796K
Article type
Communication
Submitted
06 Feb 2007
Accepted
24 Apr 2007
First published
08 May 2007

Chem. Commun., 2007, 2234-2236

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Anion templated surface assembly of a redox-active sensory rotaxane

S. R. Bayly, T. M. Gray, M. J. Chmielewski, J. J. Davis and P. D. Beer, Chem. Commun., 2007, 2234 DOI: 10.1039/B701796K

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