Issue 21, 2007
From the journal:

Chemical Communications

The active role of NHC ligands in platinum-mediated tandem hydroboration–cross coupling reactions

Vanesa Lillo,a   Jose A. Mata,b   Anna M. Segarra,a   Eduardo Peris*b  and  Elena Fernandez*a  

* Corresponding authors

a Departament de Química Física i Inorgànica. Universitat Rovira i Virgili, Pça, Imperial Tàrraco 1, Tarragona, Spain
E-mail: elenaf@quimica.urv.es
Fax: 34 977 559563
Tel: 34 977 558046

b Dpt. Química Inorgànica i Orgànica, Universitat Jaume I, Av Vicente Sos Baynat s/n, Castellón
E-mail: eperis@qio.uji.es

Abstract

Stable N-heterocyclic platinum–carbene complexes are the first example of platinum-mediated regioselective H–B addition to vinylarenes and alkynes, allowing consecutive cross coupling reactions with the same catalytic system.

Graphical abstract: The active role of NHC ligands in platinum-mediated tandem hydroboration–cross coupling reactions

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Article information

DOI
https://doi.org/10.1039/B700800G
Article type
Communication
Submitted
18 Jan 2007
Accepted
06 Feb 2007
First published
02 Mar 2007

Chem. Commun., 2007, 2184-2186

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The active role of NHC ligands in platinum-mediated tandem hydroboration–cross coupling reactions

V. Lillo, J. A. Mata, A. M. Segarra, E. Peris and E. Fernandez, Chem. Commun., 2007, 2184 DOI: 10.1039/B700800G

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