Issue 11, 2007
From the journal:

Chemical Communications

Synthesis and reactivity of alkylpalladium N-heterocyclic carbene complexes†

Oriana Esposito,a   Alexandra K. de K. Lewis,b   Peter B. Hitchcock,b   Stephen Caddick*b  and  F. Geoffrey N. Cloke*a  

* Corresponding authors

a Department of Chemistry, School of Life Sciences, University of Sussex, Falmer, Brighton, UK
E-mail: f.g.cloke@sussex.ac.uk
Fax: +44 1273 677 196
Tel: +44 1273 678735

b Christopher Ingold Laboratories, Department of Chemistry, University College London, 20 Gordon Street, London, UK
E-mail: s.caddick@ucl.ac.uk
Fax: +44 207 679 7463
Tel: +44 207 679 4694

Abstract

The transamination of alkylpalladium halide N-heterocyclic carbene complexes has enabled the isolation of products that reveal interesting insights into the factors which might be barriers to the development of a palladium-catalysed alkyl–amination reaction.

Graphical abstract: Synthesis and reactivity of alkylpalladium N-heterocyclic carbene complexes

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Article information

DOI
https://doi.org/10.1039/B700671C
Article type
Communication
Submitted
16 Jan 2007
Accepted
29 Jan 2007
First published
14 Feb 2007

Chem. Commun., 2007, 1157-1159

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Synthesis and reactivity of alkylpalladium N-heterocyclic carbene complexes

O. Esposito, A. K. D. K. Lewis, P. B. Hitchcock, S. Caddick and F. G. N. Cloke, Chem. Commun., 2007, 1157 DOI: 10.1039/B700671C

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