Magnetic canting or not? Two isomorphous 3D CoII and NiII coordination polymers with the rare non-interpenetrated (10,3)-d topological network, showing spin-canted antiferromagnetism only in the CoII system

Jian-Rong Li; Qun Yu; Ying Tao; Xian-He Bu; Joan Ribas; Stuart R. Batten

doi:10.1039/B700569E

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Magnetic canting or not? Two isomorphous 3D Co^II and Ni^II coordination polymers with the rare non-interpenetrated (10,3)-d topological network, showing spin-canted antiferromagnetism only in the Co^II system†

Jian-Rong Li,^a Qun Yu,^a Ying Tao,^a Xian-He Bu,*^a Joan Ribas^b and Stuart R. Batten^c

Author affiliations

* Corresponding authors

^a Department of Chemistry, Nankai University, Tianjin 300071, China
E-mail: buxh@nankai.edu.cn
Fax: +86-22-23502458

^b Departament de Química Inorgànica, Universitat de Barcelona Diagonal, 647, Barcelona, Spain

^c School of Chemistry, Monash University, Victoria, Australia

Abstract

The in situ solvothermal reaction of 3,4-dicyano-1,2,5-thiadiazole with MCl₂ (M = Co, Ni) and NaOH afforded two isomorphous complexes, [M₂(L)₂(H₂O)₂]_n (L = 2,1,3-thiadiazole-4,5-dicarboxylate), which exhibit a rare non-interpenetrated (10,3)-d (utp) network topology and interesting magnetic behaviors: spin-canted antiferromagnetism for the Co^II complex, but simple antiferromagnetic coupling for the Ni^II.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/B700569E
Article type: Communication
Submitted: 15 Jan 2007
Accepted: 09 Feb 2007
First published: 01 Mar 2007

Download Citation

Chem. Commun., 2007, 2290-2292

Permissions

Request permissions

Magnetic canting or not? Two isomorphous 3D Co^II and Ni^II coordination polymers with the rare non-interpenetrated (10,3)-d topological network, showing spin-canted antiferromagnetism only in the Co^II system

J. Li, Q. Yu, Y. Tao, X. Bu, J. Ribas and S. R. Batten, Chem. Commun., 2007, 2290 DOI: 10.1039/B700569E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications