Issue 18, 2007

A new coupling reaction for the synthesis of ruthenium half-sandwich complexes with sterically demanding cyclopentadienyl ligands

Abstract

The reaction of RuCl3(solv.)n with tert-butylacetylene in methanol or ethanol leads to the formation of chloro-bridged half-sandwich complexes with sterically demanding cyclopentadienyl ligands, which are of high interest as starting materials for the synthesis of novel Ru catalysts.

Graphical abstract: A new coupling reaction for the synthesis of ruthenium half-sandwich complexes with sterically demanding cyclopentadienyl ligands

Supplementary files

Article information

Article type
Communication
Submitted
22 Dec 2006
Accepted
19 Jan 2007
First published
09 Feb 2007

Chem. Commun., 2007, 1837-1839

A new coupling reaction for the synthesis of ruthenium half-sandwich complexes with sterically demanding cyclopentadienyl ligands

S. Gauthier, E. Solari, B. Dutta, R. Scopelliti and K. Severin, Chem. Commun., 2007, 1837 DOI: 10.1039/B618712A

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