The combinative use of Au(I), a skeletally flexible diphosphine and a bifunctional spacer of pyridyl carboxylate with tunable directional and donor properties has resulted in a series of structurally distinctive ensembles and Au2 metalloligands with O-donicity.
P. Teo, L. L. Koh and T. S. A. Hor, Chem. Commun., 2007, 2225 DOI: 10.1039/B618309C
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