Issue 18, 2007
From the journal:

Chemical Communications

A rational approach to the modulation of the dynamics of the magnetisation in a dysprosium–nitronyl-nitroxide radical complex†

Giordano Poneti,a   Kevin Bernot,ab   Lapo Bogani,a   Andrea Caneschi,a   Roberta Sessoli,*a   Wolfgang Wernsdorferc  and  Dante Gatteschia  

* Corresponding authors

a Department of Chemistry and INSTM Research Unit, Università di Firenze, Via della Lastruccia 3, Sesto Fiorentino, Italy
E-mail: roberta.sessoli@unifi.it
Fax: 39 055 4573372
Tel: 39 055 4573268

b Sciences Chimiques de Rennes, UMR 6226 CNRS-INSA Rennes, Equipe «Matériaux Inorganiques: Chimie Douce et Réactivité», INSA Rennes, 20 Avenue des Buttes de Coësmes, CS 14315, Rennes Cedex, France

c Laboratory Louis Nèel, CNRS, BP 166, Grenoble Cedex 9, France

Abstract

A control of the dynamics of the magnetisation is chemically achieved in a ring-like Dy-radical based molecule, allowing the estimation of the quantum tunneling frequency with a 4He-cooled susceptometer.

Graphical abstract: A rational approach to the modulation of the dynamics of the magnetisation in a dysprosium–nitronyl-nitroxide radical complex

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Article information

DOI
https://doi.org/10.1039/B617898G
Article type
Communication
Submitted
07 Dec 2006
Accepted
31 Jan 2007
First published
14 Feb 2007

Chem. Commun., 2007, 1807-1809

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A rational approach to the modulation of the dynamics of the magnetisation in a dysprosium–nitronyl-nitroxide radical complex

G. Poneti, K. Bernot, L. Bogani, A. Caneschi, R. Sessoli, W. Wernsdorfer and D. Gatteschi, Chem. Commun., 2007, 1807 DOI: 10.1039/B617898G

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