Issue 11, 2007
From the journal:

Chemical Communications

Isoquinolin-1-ylidenes as electronically tuneable ligands†

Silvia Gómez-Bujedo,a   Manuel Alcarazo,a   Christophe Pichon,‡a   Eleuterio Álvarez,a   Rosario Fernández*b  and  José M. Lassaletta*a  

* Corresponding authors

a Instituto de Investigaciones Químicas (CSIC-US), Américo Vespucio 49, Seville, Spain
E-mail: jmlassa@iiq.csic.es
Fax: +34 95 4460565

b Departamento de Química Orgánica, Univ. de Sevilla, Apdo. de Correos 553, Seville, Spain
E-mail: ffernan@us.es
Fax: +34 954624960

Abstract

The novel isoquinolin-1-ylidene ligands, introduced into Rh(I) complexes by exploiting the carbene-like reactivity of adducts 6, exhibit ligand properties similar to those of classic NHCs, and their electronic properties can be tuned by the introduction of electron-withdrawing or donating groups in the benzene ring.

Graphical abstract: Isoquinolin-1-ylidenes as electronically tuneable ligands

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Article information

DOI
https://doi.org/10.1039/B617037D
Article type
Communication
Submitted
22 Nov 2006
Accepted
14 Dec 2006
First published
10 Jan 2007

Chem. Commun., 2007, 1180-1182

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Isoquinolin-1-ylidenes as electronically tuneable ligands

S. Gómez-Bujedo, M. Alcarazo, C. Pichon, E. Álvarez, R. Fernández and J. M. Lassaletta, Chem. Commun., 2007, 1180 DOI: 10.1039/B617037D

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