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Issue 7, 2007
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Enantioselective palladium-catalysed conjugate addition of arylsiloxanes

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Abstract

The complex formed from Pd(CH3CN)4(BF4)2 and (R,R)-MeDUPHOS is a highly enantioselective catalyst for the asymmetric conjugate addition of aryltriethylsiloxanes to a variety of unsaturated ketones, lactones and lactams.

Graphical abstract: Enantioselective palladium-catalysed conjugate addition of arylsiloxanes

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Publication details

The article was received on 21 Nov 2006, accepted on 09 Jan 2007 and first published on 18 Jan 2007


Article type: Communication
DOI: 10.1039/B616969D
Citation: Chem. Commun., 2007,0, 710-712

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    Enantioselective palladium-catalysed conjugate addition of arylsiloxanes

    F. Gini, B. Hessen, B. L. Feringa and A. J. Minnaard, Chem. Commun., 2007, 0, 710
    DOI: 10.1039/B616969D

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